The explosive yield of tnt is considered to be the standard. If it contacts the eye, the eye should be irrigated immediately. A wide variety of nitro toluene options are available to you, such as industrial grade, electron grade, and medicine grade. A detailed chemical kinetic mechanism for gas phase combustion of 2,4,6trinitrotoluene tnt has been developed to explore problems of explosive performance and of soot formation during the destruction of munitions. September 8, 2009 information in this msds is from available published sources and is believed to be accurate. There are 54 suppliers who sells nitro toluene on, mainly located in asia. Disclaimer the sds samples above are collected from the internet by chemblink and displayed here for the tutorial purpose only. No warranty, express or implied, is made and labchem inc.
Di nitro toluene market size will witness a significant growth due to its increasing applications in various industries including chemical, plastics, explosives and automotive. Sigmaaldrich 244511 page 3 of 8 suitable extinguishing media use water spray, alcoholresistant foam, dry chemical or carbon dioxide. Nitrotoluene definition of nitrotoluene by merriamwebster. Tnt, or more specifically 2,4,6trinitrotoluene, is a chemical compound with the formula c 6 h 2 no 2 3 ch 3. Carcinogen selector endocrine system mammary gland. It is an intermediate in the production of various dyes. Sds of 2,4dinitrotoluene, safety data sheets, cas 121142. This pale yellow crystalline solid is well known as a precursor to trinitrotoluene tnt but is mainly produced as a precursor to toluene diisocyanate. The user must determine suitability of this information for his. Demand for luxury cars namely lexus and bmw have grown by over 15% in 2016 with increase in disposable income that has given a positive outlook to di nitro toluene market. The chemical identifier fields include common identification numbers, the nfpa diamond u. For small spills of 2nitrotoluene, take up with vermiculite, dry sand, or earth and place into containers for later disposal.
Absorb spill using an absorbent, noncombustible material such as earth, sand, or vermiculite. Sigmaaldrich offers a number of 2,6dichlorotoluene products. The substance identity section is calculated from substance identification information from all echa databases. Rapporteur for the risk assessment of 2,4dinitrotoluene is spain. Hazardous combustion products hazardous decomposition products formed under fire conditions. If it contacts the skin, the area should be washed with soap. Use proper personal protective equipment as indicated in section 8. Identification of the substancemixture and of the company. Read the product manufacturers material safety data. Take measures to prevent the build up of electrostatic. Slowly combine 150 ml of 68% nitric acid with 180 ml of sulfuric acid. Jun 18, 2010 for the best answers, search on this site if you treat the benzene with hno3,h2so4 for the first step, youll have c6h5no2. Incompatible with oxidizing agents, strong bases,sulfuric acid, reducing agents, hydrogen, sodium.
A mononitrotoluene carrying a nitro group at position 3. Voranate t80 type i and type ii tdi are part of the family of quality aromatic isocyanates available from dow. Toluene, a flammable liquid with a pungent odor, is widely employed as an organic solvent. All explosives are dangerous and must be handled carefully and used following approved safety. However, we make no warranty of merchantability or any other. Identification of the substancemixture and of the companyundertaking 1. Toluene does not cause the severe injury to the bone marrow that is characteristic of benzene poisoning. Synthesis of onitrotoluene and pnitrotoluene thomas. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Dispose of contentscontainer according to section of the sds. H410 very toxic to aquatic life with long lasting effects. In case of skin contact wash off with soap and plenty of water. Nmethylnnitrosoptoluenesulfonamide msds special notice. Di nitro toluene dnt is a solid crystalline organic compound with pale yellow colour and fabricated as precursor for toluene diisocyanate tdi and trinitrotoluene tnt. Structure, properties, spectra, suppliers and links for. If inhaled if breathed in, move person into fresh air. The national response center database contains reports of two spills reported as onitrotol. Di nitro toluene market size industry trends analysis. The substance identifiers displayed in the infocard are the best available substance name, ec number, cas number andor the. Although kidney toxicity has not been common in cases of occupational toluene exposure, there has been at least one report of renal toxicity following a 40year occupational toluene exposure.
Material safety data sheet trinitrotoluene tnt msds. Ou chemical safety data no longer updated more details. Chemspider does not currently have any image data for this record. Page 4 of 7 msds toluene di isocyanate incompatibles such as moisture.
Safety data sheet northwest missouri state university. The information in cameo chemicals comes from a variety of data sources. Aniline material safety data sheet cas no 62533 sdsmsds. Now if youre adding ch3cl with friedelcraftsalcl3 reaction, youll have the m nitro toluene, because the nitro radical is a secondary substituent, and all the ring processes will end in meta form. Material safety data sheet nitrobenzene msds section 1. Sds of 3nitrooxylene, safety data sheets, cas 83410. A liquid is typically considered a nonconductive, static accumulator if its conductivity is below 100 psm 100x10e12 siemens per meter and is. Application toluene undergoes alkylation in the presence of modified zsm zeolite socony mobil5class zeolite catalysts to form pxylene with high selectivity.
The principle application involves its sulfonation to give the 4nitrotoluene2sulfonic acid with the so 3 h group adjacent to methyl. Trinitrotoluene tnt 118967 not available section 3. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. Department of transportation hazard labels, and a general description of the chemical. Excerpt from erg guide 152 substances toxic combustible. It has a role as an environmental contaminant and a carcinogenic agent. General description 2nitrotoluene is a nitroaromatic compound. As an immediate precautionary measure, isolate spill or leak area in all directions for at least 50 meters 150 feet for liquids and at least 25 meters 75 feet for solids. Vinmar international is a global marketing, distribution and project development company that brings value to the worlds leading producers and users of petrochemical products through tailored business solutions. Pour 156 ml of toluene into a reflux apparatus with open pressure equalized addition funnel, place the flask in saltice slush. Avoid runoff into storm sewers and ditches which lead to waterways.
Section 6 accidental release measures general information. By treating toluene with nitric acid, three nitro groups attach themselves to the molecule in this manner. Multifunctional magnetic resins having high surface area and ion exchange efficiency gma301 and gma302 were developed and were tested for the desorption of 2nitrotolene. Rapporteur for the risk assessment of 2,4 dinitrotoluene is spain. This pale yellow crystalline solid is well known as a precursor to trinitrotoluene but is mainly produced as a precursor to toluene diisocyanate. Nmethylnnitrosoptoluenesulfonamide msds msdsdigital. Dike to prevent land spills of 3nitrotoluene from entering water sources or sewers, and take up by absorbing the material in vermiculite, dry sand, or earth.
The second ranked application involves its disproportionation to a mixture of benzene and xylene. Nitration of toluene give mono, di, and trinitrotoluene, all of which are widely used. Panoli intermediates manufacturers and exporters of dye intermediate, chemicals manufacturer, industrial chemicals manufacturers, chemicals supplier, industrial dye intermediate, supplier of chemicals, chemical exporter, chemicals suppliers, industrial chemicals, dye intermediate manufacturer, indian industrial chemicals, industrial chemicals, industrial chemicals and dye, integrated. The information provided in this safety data sheet is correct to the best of our knowledge, information and belief at the date of its publication. Thermodynamic properties of intermediate and radical species are estimated by group additivity. The carcinogen selector gives researchers the ability to select carcinogens by the mouse organs that they promote cancer in. Together with other isomers, 4nitrotoluene is prepared by nitration of toluene. Special protective equipment for firefighters wear self contained breathing apparatus for fire fighting if necessary. The information contained in this material safety data sheet is based upon available data and believed to be correct. Toluene is mainly used as a precursor to benzene via hydrodealkylation. Since that time new data have become available, which have been incorporated in this monograph,and taken into consideration in the present evaluation.
This pale yellow crystalline solid is well known as a precursor to. This yellow solid is sometimes used as a reagent in chemical synthesis, but it is best known as an explosive material with convenient handling properties. Safety data sheet according to 29cfr19101200 and ghs rev. Firstaid measures general advice if symptoms persist, call a physician. Symptoms include, anoxia, weakness or dizziness, nausea and vomiting. Page 1 of 10 safety data sheet toluene diisocyanate. Both type i and type ii are a mixture of 2,4 and 2,6isomers of tdi in a ratio, by weight, of 80 percent and 20 percent, respectively. The crystals will start to melt slowly, so put them into a storage container fast. These are primarily used to manufacture polyurethane foams. Show this safety data sheet to the doctor in attendance.304 663 872 405 343 314 665 1219 28 1091 1386 642 243 1150 987 1411 954 1110 654 75 623 612 598 893 848 505 567 1266 1148 1050 85 399 328 131 913 734 1175 512 1385 165 1193 614 520 1106